diff --git a/artifacts/collated.tsv b/artifacts/collated.tsv
index e1d86bb..fd0ba55 100644
--- a/artifacts/collated.tsv
+++ b/artifacts/collated.tsv
@@ -1,4 +1,7 @@
 #prefix	did	when	nextofkin
+cas	152175-96-7		12184-96-2
+cas	152175-97-8		12596-12-2
+cas	155313-22-7		12596-15-5
 cas	2270854-18-5		60433-72-9
 cas	725200-57-7		1333-74-0
 chebi	443041		
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index 3349ae6..3629437 100644
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